Halon 1301 is installed and used in fixed
flooding systems for extinguishing flammable
liquid fires. Halon 1211 is not used in total
flooding systems. Its lower volatility, plus a high
liquid density, permits the agent to be sprayed as
a liquid and therefore propelled into the fire zone
to a greater extent than is possible with other
gaseous agents. Halon 1211 will replace Purple-
K-Powder (PKP) in twin-agent systems installed
on mobile fire-fighting apparatus on aircraft
carriers.
Steam. Steam smothers a fire by reducing
the concentration of oxygen or the gaseous phase
of the fuel in the air to the point that combustion
stops. As long as the steam blanket is maintained,
it will prevent reignition.
Since steam is a vapor when applied, it
provides little cooling. Additionally, steam
condenses when its supply is shut off. Its volume
decreases rapidly and combustible vapors and air
rush in to replace it. A fire can reflash if it has
not been completely extinguished and cooled. The
temperature of steam itself is high enough to
ignite many liquid fuels. Steam is hazardous to
personnel because the heat it carries can inflict
severe burns.
Dry Chemical Extinguishing Agent. PKP
is a dry chemical principally used as a fire-
extinguishing agent for flammable liquid fires. It
is used in portable extinguishers and handheld
hose-line systems aboard ship.
Various additives are mixed with PKP base
materials to improve their storage, flow, and
water-repellency characteristics. The most com-
monly used additives are silicones, which coat the
particles of PKP to make them free flowing and
resistant to the caking effect of moisture and
vibration.
When PKP is applied to fire, the dry chemical
extinguishes the flame by breaking the combus-
tion chain. PKP does not have cooling capability.
When PKP is applied, an opaque cloud is formed
in the combustion areas. This cloud limits the
amount of heat that can be radiated back to the
heart of the fire. Less fuel vapor is produced
because of reduced radiant heat.
PKP attacks the chain reaction required to
sustain a fire. It is believed that PKP reduces the
ability of the molecular fragments to recombine,
thereby breaking the chain reaction.
PKP is primarily used to extinguish flammable
liquid fires but can also be used on electrical fires
(class C). PKP is highly effective in extinguishing
both flammable liquid pool fires and oil spray
fires. Although PKP can be used on electrical
fires, it will leave a residue that may be hard to
clean. PKP can be used in the galley for fighting
fires on such items as the cooking hood, ducts,
and ranges.
WARNING
The ingredients presently used in PKP are
nontoxic. However, the discharge of large
quantities of PKP may cause temporary
breathing difficulty during and immediately
after discharge and may seriously interfere
with visibility.
The following is a list of limitations for PKP
use.
1.
2.
3.
4.
5.
6.
PKP is not effective on materials that con-
tain oxygen.
PK should not be used in installations
where relays and delicate electrical contacts
are present.
PKP is not effective on combustible metals
and may cause a violent reaction.
Where moisture is present, PKP may com-
bine with the moisture to corrode or stain
surfaces on which it settles; when possible,
PKP should be removed from all surfaces.
PKP does not produce a lasting inert at-
mosphere above the surface of a flammable
liquid; consequently, its use will not result
in permanent extinguishment if ignition
sources such as hot metal surfaces or
persistent electrical arcing are present.
PKP is not effective on fires involving
ordinary combustibles (class A). However,
it can be used to knock down a flaming
fire, keeping it under control, until hose
lines are advanced to the scene.
Aqueous Potassium Carbonate. Aqueous
potassium carbonate (APC) is used aboard ships
for extinguishing burning cooking oil and grease
in deep fryers and galley ventilation exhaust ducts.
An APC solution consists of 42.2 percent K2CO3
and 57.8 percent water. Alkaline solutions such
as APC are often used in combating liquid grease
fires involving unsaturated animal fat and
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