6-9used in an unventilated space under any circumstances.Special clothing requirements also must be observedwhen using some solvents. As a petty officer, youMUST make sure all safety precautions are observed atall times. Laxity on anyone’s part could cause a mishap,resulting in injuries or even deaths. By observing safetyprecautions, you and your people will reduce mishapsand save lives.Damage to containers, including dents, pitting, rust,creases, cracks, and damage to closures and gaskets,may lead to leakage and dangerous spills. Containers inflammable liquid stowage facilities will be inspectedweekly. Containers of other hazardous materials will beinspected monthly and inventoried quarterly. NSTM,chapter 670, describes proper stowage, handling,container inspection, and disposal of hazardous general-use combustibles.Types of solventsAs mentioned throughout this chapter, the Navyuses many types of solvents for a multitude of cleaningassignments. Many of these solvents are highly toxic andsome are highly flammable. You must take special carewhen using many of these solvents; make sure you storethem in cool, dry areas. NSTM, chapter 631, contains alist of approved solvents and their flash points (lowesttemperature at which vapors ignite in air when exposedto flame). Figure 6-4 shows a list of commonly usedsolvents approved by the Navy and the flash points ofthese solvents. NSTM, chapter 670, describes properstowage, handling, and disposal of these solvents.Most cleaning solvents contain toxic substances.These substances can cause injuries if they are inhaled,absorbed by the skin, or ingested. All toxic materialsmust be handled carefully to prevent injury. Thefollowing paragraphs contain information about twogeneral categories of toxic cleaning solvents. There isanother type—fluorocarbon refrigerants and solvents;however, special approval is required to obtain and usethem. If you have any questions about the solvent youare going to use, check the maintenance requirementcards (MRCs) for the task; ask your supervisor; or checkthe NSTM, chapters 631 and 670.CHLORINATED-CLEANING SOLVENTS.—Chlorinated-cleaning solvents can be highly toxic if usedimproperly. They may be irritating to the skin and toxicif ingested. Toxic vapors may cause damage to thelungs, eyes, and nervous system when the vapors arepresent in confined spaces, in spaces with inadequateventilation, or when the vapor concentration is increasedby heating. Solvents decompose at high temperaturesand produce gases more toxic than the solventsthemselves. Solvents react with alkalies, oxidizers, andpowdered metals to produce toxic gases.Common types of chlorinated-cleaning solvents aretrichloroethane (inhibited methylchloroform),trichloroethylene, tetrachloroethane, and tetra-chloroethylene (perchloroethylene, dry-cleaning solvent).Because of the extreme dangers involved, the Navyseverely restricts the use of these solvents. For detailedrestriction information on solvents, refer to NSTM,chapter 670, section 3.Never stow chlorinated-cleaning solvents near heatsources or open flames. Do not allow them to come incontact with hot surfaces. Make sure stowage areas arewell ventilated and monitored regularly by the gas-freeengineer. Additionally, do not stow these solvents nearincompatible materials. Incompatible materials includestrong alkalies, such as sodium hydroxide; oxidizers,such as calcium hypochlorite and sodium nitrate; andpowdered metals, such as aluminum.When handling chlorinated-cleaning solvents, wearthe following personal protective equipment (PPE):Neoprene glovesSafety goggles that will protect against splashesor a face shieldA chemical cartridge respirator for protectionagainst small amounts of organic vapors or forprotection for a short duration; or an air line respirator(or some other type of supplied-air respirator) if use isextensive or in a confined spaceCoverallsMake sure work areas in which you use chlorinated-cleaning solvents have proper ventilation.
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