Safety goggles that will protect against splashes,
or a face shield
A chemical cartridge respirator for protection
against small amounts of organic vapors or for
protection for a short duration; or an air-line
respirator (or some other type of supplied-air
respirator) if use is extensive or in a confined
space
Coveralls
Make sure work areas in which you use chlorinated
cleaning solvents have proper ventilation. For enclosed
spaces, an air change every 3 minutes is recommended.
Consult the gas free engineer to determine if the
ventilation is adequate.
Organic Cleaning Solvents
Organic cleaning solvents include the following:
Toluene
Xylene
Some alcohols
Acetone
Methyl ethyl ketone
Ethyl acetate
Dry-cleaning solvent
Kerosene
Petroleum
Ether
Turpentine
Morpholine and other related compounds
These compounds are highly flammable and highly to
moderately toxic. Some are also corrosive. Inhalation of
concentrated vapors may cause dizziness, nausea, or
vomiting.
Organic cleaning solvents should be stowed as
follows:
Stow organic cleaning solvents in a flammable
liquid storeroom, ready service storeroom, or a
flammable locker.
Keep them away heat, open flames, or
spark-producing devices.
Stow them away from oxidizers, such as calcium
hypochlorite, sodium nitrate, and hydrogen
peroxide.
When handling organic cleaning solvents, wear the
following PPE:
Neoprene gloves
Safety splash goggles
Protective coveralls (recommended)
In addition, if vapors accumulate over 100 parts per
million (ppm), wear an OBA and notify the gas free
engineer.
Fluorocarbon Refrigerants and Solvents
Fluorocarbon refrigerants and fluorocarbon
solvents, such as trichlorotrifluoroethane (Freon 113,
Freon TF, Genetron 113, R-113), are commonly found
aboard ship. They are used in food storage compart-
ments and air-conditioned spaces and as solvents in
engineering spaces.
Fluorocarbon vapors have the following
characteristics:
They are colorless and almost odorless.
They cannot be detected without special
instruments.
They are nonflammable and nonexplosive;
however, exposure to flames or hot surfaces will
cause these compounds to generate hydrogen
chloride, hydrogen fluoride, and other
poisonous gases.
They arent irritating, but contact may cause
frostbite.
Operations involving trichlorotrifluoroethane (Freon
113) are considered hazardous. An industrial hygienist
or a gas free engineer must evaluate and approve these
operations to ensure the work process meets safety
requirements.
18-9
Student Notes: